TY  - SER
AU  - Atwood,Alyssa R.
AU  - Volkman, John K.
AU  - Sachs,Julian P.
TI  - Characterization of unusual sterols and long chain diols, triols, keto-ols and n-alkenols in El Junco Lake, Galápagos
U1  - 551.9 23
PY  - 2014///
KW  - Characterization
KW  - Caracterización
KW  - Sterols
KW  - Esteroles
KW  - Triols
KW  - Keto-ols
KW  - N-alkenols
KW  - Junco Lake
KW  - Lago Junco
KW  - Galápagos
N2  - A variety of lipid biomarkers were identified in sediments from El Junco Lake, Galápagos and their sources investigated for potential use in paleoclimate applications. A series of unusual sterols was also found, including 4 a-methylgorgostanol, reported in only four species of dinoflagellates to date. We also tentatively assigned 22,23-methylene-4a-methyl-24-ethylcholest-5-en-3b-ol, the mass spectrum of which matched a sterol found in resting cysts of the dinoflagellate Peridinium umbonatum. In addition, we identified the novel sterol 4a,22,23,24-tetramethyl-5a-cholest-22E-en-3b-ol. Based on the unique sterol distribution, we hypothesize that a dinoflagellate from the genus Peridinium was the primary source of dinosterol and the novel sterols throughout the sediment record. The source specificity and abundance throughout the 3.7 m of recovered sediment make dinosterol an excellent target for hydrogen isotope analysis for use as a paleohydrological proxy in future studies. The abundant C 1,x20-diols and keto-ols, C29 9,10-diol and C2930 1,x9,x10-triol likely derive from the ferns Azolla microphylla and Cyathea weatherbyana, while sources of the C30 1,x16-diol and keto-ol, C1,x18-diol and keto-ol, and theC30–C32 32n-alken-1-ols are likely limited to aquatic microalgae. Due to their source specificity, these diol, triol, keto-ol, and n-alkenol biomarkers present further tools for studying past environmental and climatic change
UR  - http://dx.doi.org/10.1016/j.orggeochem.2013.11.004
ER  -